syscokid
Ambassador of War & Peace
First of all, the TubeStore link works. I still need to read it though.Damn, there's some miss-information creeping into this thread,,, and I do not like my TTR buddy's to be
miss-informed.
Ok, firstly folks, the type of valves we use in our guitar amp use Barium for gettering purposes. That deposit on the glass, known as "getter flash" is this barium metal that has been induction heated to vaporise it & deposit it on the glass.
While it most usually has a shiny silver appearance, the colour can actually vary from a grey colour through to black. The colour of the getter flashing is totally dependant on how quickly it is heated during the gettering process.
The Tube Store has an article on there site, entitled "blue glow in tubes, tube getters & other info" which also explains this, & also links a quite in depth article on valve gettering, that I will attempt to link for you all Blue Glow in Tubes, Tube Getters, and other Info - www.thetubestore.com If the link does work (I'm a digital dummy) the article should be easily found.
Barium is a "reactive" metal, hence its use for gettering in valves.
During manufacture of our valves, after the outgassing process & sealing of the glass envelope, there is still some residual air left inside the valve bottle. Also, during use, when the valve is heated, impurities & gasses continue to evolve from the metals of the elements etc.
The barium metal reacts with all of these & thus gets them out of the vaccum. So, the barium getter flashing is slowly used up. This can be seen by the barium getter flashing taking on an opaque, see-through appearance, starting at the very edge of the getter flashing where the barium deposit is thinnest, progressively making its way to the centre of the getter flashing where the barium deposit is thickest.
Easily seen hereView attachment 71925
And hereView attachment 71926
Note how in both these pics we can see the ring shaped "halo" getter clearly visible at the top inside the glass bottle.
When new, viewed from the side like this, the getter flashing would have had it's edge just very slightly above these "halo" getters. If you look carefully, you can make out that the opaque colouring extends down to just above the getters. So we can see that the barium getter flashing has been used up in this area.
To get an idea how slowly this getter flashing is used up, just take a look at some power tubes you've installed/had installed & know roughly how many (hundreds or thousands of) hours you have put on them. Cheers
Edit:
You may have heard about tubes that "go gassy." This is like where the bottle develops a leak or elements within the tube emit a heap of gass. This can be seen as the getter flash taking on a white appearance, seen hereView attachment 71929
Cheers
Barium Getter Flashing: So, the amount of flashing diminishes as the tube is used up?

