I would like to run a line out from my Marshall PB 100 attenuator.
A way to control the volume from the new line out would be useful as well.
So what I'm really trying to say is:
@Amp Mad Scientist , could you please help me out and walk me through this procedure?
Thanks for any help or input.
Though I'm not familiar with a lot off attenuator circuits (including the Power Brake), of the ones that I am familiar with, the line out circuitry is usually taken directly off the input to the attenuator, so is "pre attenuation". The line out circuit is typically a resistive voltage divider network that will "divide" off a signal that is in the range of 1/10th the amps output voltage. As such, the attenuator's line out is essentially the same thing as an amplifiers line out that is derived from the secondary winding of the output transformer. Because the line out circuit is also essentially in parallel with the speakers (load), the resistance of the voltage divider network must be sufficiently high so as to not mess too much with the speaker loading (impedance). Ideally the line out circuitry would feature a volume control, though this isn't always the case. Some also feature tone controls.
Here's a couple of example schematics I just pulled off the net.
The first is the Weber Mass 100 that features an adjustable level (volume control) line out with a switchable tone control stack.

As can be seen, the line out circuitry is directly off the attenuator input & aside from the switchable tone stack, the circuitry is very simple.
The second is the much simpler line out circuit used in the Weber MiniMass, fixed level (no volume control) & no tone control.

The voltage divider is made up of a 10k & 4k7 resistor, again directly off the attenuator input.
I use a Weber Mass 200 attenuator that feature an adjustable (volume control) line out with an adjustable treble correction tone control. I could draw the schematic from if you like.
I'm sure you could find many, many more line out circuit examples on the net to take ideas from. Hope this helps. Cheers